Neon Genesis Evangelion - Season 1 - Eps 22: Don't Be.
Asuka's synch rate is on a downward spiral after her defeat at the hands of the Fourteenth Angel, Zeruel, and her frustration with Rei, Shinji, Misato and Ryouji is on the rise. Angrier and more disturbed than ever, she is forced to relive her dark, traumatic past during the encounter with the Fifteenth Angel, Arael.
About Neon Genesis Evangelion

Title: Neon Genesis Evangelion
First Air Date: 1995-10-04
Last Air Date: 1996-03-27
Status: Ended
Rating: 8.592/10 (from 1780 votes)
Language: JA
Seasons: 1
Total Episodes: 26
Network: TV Tokyo
Genres: Sci-Fi & Fantasy, Animation, Drama
Production Companies: GAINAX
Synopsis
At the turn of the century, the Angels returned to Earth, seeking to wipe out humanity in an apocalyptic fury. Devastated, mankind's last remnants moved underground to wait for the day when the Angels would come back to finish the job. Fifteen years later, that day has come... but this time, humanity is ready to fight back with terrifying bio-mechanical weapons known as the Evangelions. Watch as Shinji, Rei, Asuka and the rest of the mysterious shadow agency Nerv battle to save earth from total annihilation.
Cast

Megumi Ogata
Shinji Ikari (voice)

Kotono Mitsuishi
Misato Katsuragi (voice)

Megumi Hayashibara
Rei Ayanami (voice)

Yuko Miyamura
Asuka Langley Soryu (voice)

Yuriko Yamaguchi
Dr. Ritsuko Akagi (voice)

Fumihiko Tachiki
Gendo Ikari (voice)

Motomu Kiyokawa
Kozo Fuyutsuki (voice)

Miki Nagasawa
Maya Ibuki (voice)