The Secret Squirrel Show - Season 1 - Eps 63: Pussycat Man
The cops call on Pussycat Man to stop the two-headed villain, the Thinker. Winnie, a big fan of Pussycat Man, hears about it over the radio and decides to go meet him. She accidentally makes him faint and decides to take his place to stop the Thinker from robbing a bank. Winnie, as Pussycat Man, foils the robbery attempt using her witchcraft. Afterwards, she convinces the real Pussycat Man that he stopped the robbers.
About The Secret Squirrel Show

Title: The Secret Squirrel Show
First Air Date: 1965-10-02
Last Air Date: 1966-12-25
Status: Ended
Rating: 7.4/10 (from 67 votes)
Language: EN
Seasons: 1
Total Episodes: 78
Network: NBC
Genres: Animation, Comedy, Action & Adventure, Crime, Kids, Family
Production Companies: Screen Gems Television, Hanna-Barbera Productions, NBC
Synopsis
The half-hour The Secret Squirrel Show included three individual cartoon segments: "Secret Squirrel", "Squiddly Diddly" and "Winsome Witch".
Cast

Mel Blanc
Secret Squirrel

Paul Frees
Double-Q

John Stephenson
Chief Winchley

Dick Beals
Clyde