Saint Seiya - Season 1 - Eps 13: Burn! Flaming Attack!
In this episode, Shiryu challenges the Black Dragon, while Shun tries to save Seiya, who is slowly dying because of Black Pegasus' Black Death Horror. Shiryu, still weak because of his blood loss, almost sacrifices his life for friendship (which Black Dragon can't understand why, since he doesn't believe in such thing as friendship).
About Saint Seiya

Title: Saint Seiya
First Air Date: 1986-10-11
Last Air Date: 1989-04-01
Status: Ended
Rating: 8.5/10 (from 1298 votes)
Language: JA
Seasons: 1
Total Episodes: 114
Network: tv asahi
Genres: Animation, Drama, Action & Adventure, Sci-Fi & Fantasy
Production Companies: Toei Animation
Synopsis
Ages ago, the goddess Athena was served by fighters called Saints who channeled the power of the Cosmos within them. Now a youth named Seiya has trained to become a Saint himself by earning the mystical Cloth of Pegasus. He is joined by other Saints with Cloths of their own to fight for Athena.
Cast

Toru Furuya
Seiya (voice)

Hirotaka Suzuoki
Shiryu (voice)

Ryo Horikawa
Shun (voice)

Koichi Hashimoto
Hyoga (voice)

Hideyuki Hori
Ikki (voice)

Keiko Han
Saori Kido (voice)

Hideyuki Tanaka
Narrator / Aiolia (voice)

Mami Koyama
Shaina (voice)

Yuriko Yamamoto
Marin (voice)

Kazuyuki Sogabe
Saga / Kanon (voice)