I Love Lucy - Season 4 - Eps 16: L.A. at Last
Lucy arrives in Hollywood with stars in her eyes. She heads for The Brown Derby, a celebrity hangout, where she encounters Eve Arden and William Holden -- and inadvertently presents Holden with a custard pie in the face. Hollywood legends William Holden and Eve Arden guest-star as themselves.
About I Love Lucy

Title: I Love Lucy
First Air Date: 1951-10-15
Last Air Date: 1957-05-06
Status: Ended
Rating: 7.9/10 (from 226 votes)
Language: EN
Seasons: 7
Total Episodes: 180
Network: CBS
Genres: Comedy, Family
Production Companies: Desilu Productions
Synopsis
Cuban Bandleader Ricky Ricardo would be happy if his wife Lucy would just be a housewife. Instead she tries constantly to perform at the Tropicana where he works, and make life comically frantic in the apartment building they share with landlords Fred and Ethel Mertz, who also happen to be their best friends.
Cast

Lucille Ball
Lucy Ricardo

Desi Arnaz
Ricky Ricardo

Vivian Vance
Ethel Mertz

William Frawley
Fred Mertz