Pinky and the Brain - Season 1 - Eps 10: TV or Not TV
Brain develops a special pair of dentures that can produce a smile that can hypnotize anyone who is not wearing a special pair of sunglasses. In order to take over the world, he needs people to see the mesmerizing smile. He figures that he needs to get on TV and in order to do that he has to become a celebrity.
About Pinky and the Brain

Title: Pinky and the Brain
First Air Date: 1995-09-09
Last Air Date: 1998-11-04
Status: Ended
Rating: 7.6/10 (from 699 votes)
Language: EN
Seasons: 5
Total Episodes: 95
Network: The WB
Genres: Animation, Comedy, Family, Sci-Fi & Fantasy, Kids
Production Companies: Warner Bros. Television, Amblin Entertainment, Warner Bros. Animation
Synopsis
Pinky and Brain are genetically enhanced laboratory mice who reside in a cage in the Acme Labs research facility. Brain is self-centered and scheming; Pinky is good-natured but feebleminded. In each episode, Brain devises a new plan to take over the world, which ultimately ends in failure, usually due to Pinky's idiocy, the impossibility of Brain's plan, Brain's own arrogance, or just circumstances beyond their control.
Cast

Rob Paulsen
Pinky (voice)

Maurice LaMarche
The Brain (voice)