Alias - Season 2 - Eps 21: Second Double
Sydney begins to question Will's identity when he's arrested for espionage, under suspicion of being a double. Meanwhile Sark and Irina plot to recover the Rambaldi heart, and Sloane makes Jack a business proposal.
About Alias

Title: Alias
First Air Date: 2001-09-30
Last Air Date: 2006-05-22
Status: Ended
Rating: 6.736/10 (from 645 votes)
Language: EN
Seasons: 6
Total Episodes: 105
Network: ABC
Genres: Action & Adventure, Drama
Production Companies: Bad Robot, Touchstone Television
Synopsis
Sydney Bristow, an agent who has been tricked to believe she is working for the U.S. government, is actually working for a criminal organization named the Alliance of Twelve. Upon learning this, Sydney becomes a double agent for the real CIA.
Cast

Jennifer Garner
Sydney Bristow

Michael Vartan
Michael Vaughn

Victor Garber
Jack Bristow

Ron Rifkin
Arvin Sloane

Carl Lumbly
Marcus Dixon

Kevin Weisman
Marshall Flinkman

Rachel Nichols
Rachel Gibson

Amy Acker
Kelly Peyton